• 文献标题:   A stacked structure comprising 3-dimensional nitrogen-doped graphene, silicon microchannel plate, and TiO2 for high-performance anode in lithium-ion battery
  • 文献类型:   Article
  • 作  者:   MIAO FJ, MIAO R, YU Z, SHI CP, ZHU L, CHU PK
  • 作者关键词:   silicon mcp, nanocomposite, lithiumion batterie, graphene, silicon microchannel plate
  • 出版物名称:   MATERIALS EXPRESS
  • ISSN:   2158-5849 EI 2158-5857
  • 通讯作者地址:   Qiqihar Univ
  • 被引频次:   2
  • DOI:   10.1166/mex.2019.1533
  • 出版年:   2019

▎ 摘  要

A hybrid electrode composed of silicon microchannel plates (Si MCPs) coated with nitrogen-doped graphene and TiO2 is prepared and used as the anode in a lithium-ion battery. The materials are characterized systematically by scanning electron microscopy, Raman scattering spectroscopy, X-ray photoelectron spectroscopy, and electrochemical techniques. The unique porous and ordered nanostructure of the TiO2/N-graphene/Si-MCP nanocomposite provides short paths for diffusion of Li ions and immobilized active sites, whereas N-doped graphene facilitates fast charge transportation. The synergetic effects result in high reversible specific capacities and stability. Owing to the compatibility with semiconductor processing and devices, the concept and technique have large potential in large-scale fabrication of high-performance anodes of lithium-ion batteries, especially those integrated into microelectronic chips.