• 文献标题:   Study of a graphene-like anode material in N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   GALINSKI M, ACZNIK I
  • 作者关键词:   graphite oxide, graphene sheet, ionic liquid, lithiumion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Poznan Univ Tech
  • 被引频次:   5
  • DOI:   10.1016/j.jpowsour.2012.05.039
  • 出版年:   2012

▎ 摘  要

Graphene nanosheets or reduced graphite oxide materials recently have attracted great attention because of their excellent electrochemical properties such as excellent electrical conductivity and high specific capacity originating from their structure, i.e., two-dimensional layers with one-atomic thickness. This work is focused on reduced graphite oxide (RGO) applied as negative electrode in Li-ion cell with ionic liquid (N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide, Py13TFSI) as electrolyte. Three different electrochemical techniques, e.g., galvanostatic charging/discharging, cyclic voltammetry and electrochemical impedance spectroscopy were applied for full electrochemical characterisation of these materials. The results proved that RGO gives good reversible capacity of ca. 550 mAh g(-1) (at current density of 50 mA g(-1)) working together with the ionic liquid. This value is comparable to that characteristic for cells operating with conventional electrolyte (cyclic carbonates). (c) 2012 Elsevier B.V. All rights reserved.