• 文献标题:   Ultrathin single-crystalline TiO2 nanosheets anchored on graphene to be hybrid network for high-rate and long cycle-life sodium battery electrode application
  • 文献类型:   Article
  • 作  者:   SHOAIB A, HUANG YX, LIU J, LIU JJ, XU M, WANG ZH, CHEN RJ, ZHANG JT, WU F
  • 作者关键词:   ultrathin singlecrystalline tio2 nanosheet, graphene, 3d hybrid network, intimate stacking, sodium ion battery anode
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   36
  • DOI:   10.1016/j.jpowsour.2016.12.077
  • 出版年:   2017

▎ 摘  要

In view of the growing concern about energy management issues, sodium ion batteries (SIBs) as cheap and environmentally friendly devices have increasingly received wide research attentions. The high current rate and long cycle-life of SIBs are considered as two key parameters determining its potential for practical applications. In this work, the rigid single-crystalline anatase TiO2 nanosheets (NSs) with a thickness of 4 nm has been firstly prepared, based on which a stable nanostructured network consisting of ultrathin anatase TiO2 NSs homogeneously anchored on graphene through chemical bonding (TiO2 NSs-G) has fabricated by hydrothermal process and subsequent calcination treatment. The morphology, crystallization, chemical compositions and the intimate maximum contact between TiO2 NSs and graphene are confirmed by TEM, SEM, XRD, XPS and Raman characterizations. The results of electrochemical performance tests indicated that the TiO2 NSs-G hybrid network could be consider as a promising anode material for SIBs, in assessment of its remarkably high current rate and long cycle-life aside from the improved specific capacity, rate capability and cycle stability. (C) 2016 Elsevier B.V. All rights reserved.