• 文献标题:   The Role of Oxidative Debris on Graphene Oxide Films
  • 文献类型:   Article
  • 作  者:   LOPEZDIAZ D, VELAZQUEZ MM, DE LA TORRE SB, PEREZPISONERO A, TRUJILLANO R, FIERRO JLG, CLARAMUNT S, CIRERA A
  • 作者关键词:   graphene oxide, monolayer, oxidative debri, surface chemistry, thin film
  • 出版物名称:   CHEMPHYSCHEM
  • ISSN:   1439-4235 EI 1439-7641
  • 通讯作者地址:   Univ Salamanca
  • 被引频次:   18
  • DOI:   10.1002/cphc.201300620
  • 出版年:   2013

▎ 摘  要

We study the effect of oxidative impurities on the properties of graphene oxide and on the graphene oxide Langmuir-Blodgett films (LB). The starting material was grupo Antolin nanofibers (GANF) and the oxidation process was a modified Hummers method to obtain highly oxidized graphene oxide. The purification procedure reported in this work eliminated oxidative impurities decreasing the thickness of the nanoplatelets. The purified material thus obtained presents an oxidation degree similar to that achieved by chemical reduction of the graphite oxide. The purified and non-purified graphene oxides were deposited onto silicon by means of a Langmuir-Blodgett (LB) methodology. The morphology of the LB films was analyzed by field emission scanning microscopy (FE-SEM) and micro-Raman spectroscopy. Our results show that the LB films built by transferring Langmuir monolayers at the liquid-expanded state of the purified material are constituted by close-packed and non-overlapped nanoplatelets. The isotherms of the Langmuir monolayer precursor of the LB films were interpreted according to the Volmer's model.