• 文献标题:   SnS2 Nanoplatelet@Graphene Nanocomposites as High-Capacity Anode Materials for Sodium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   XIE XQ, SU DW, CHEN SQ, ZHANG JQ, DOU SX, WANG GX
  • 作者关键词:   anode material, graphene, nanostructure, sodium ion batterie, tin sulfide
  • 出版物名称:   CHEMISTRYAN ASIAN JOURNAL
  • ISSN:   1861-4728 EI 1861-471X
  • 通讯作者地址:   Univ Technol Sydney
  • 被引频次:   110
  • DOI:   10.1002/asia.201400018
  • 出版年:   2014

▎ 摘  要

Na-ion batteries have been attracting intensive investigations as a possible alternative to Li-ion batteries. Herein, we report the synthesis of SnS2 nanoplatelet@graphene nanocomposites by using a morphology-controlled hydrothermal method. The as-prepared SnS2/graphene nanocomposites present a unique two-dimensional platelet-on-sheet nanoarchitecture, which has been identified by scanning and transmission electron microscopy. When applied as the anode material for Na-ion batteries, the SnS2/graphene nanosheets achieved a high reversible specific sodium-ion storage capacity of 725mAhg(-1), stable cyclability, and an enhanced high-rate capability. The improved electrochemical performance for reversible sodium-ion storage could be ascribed to the synergistic effects of the SnS2 nanoplatelet/graphene nanosheets as an integrated hybrid nanoarchitecture, in which the graphene nanosheets provide electronic conductivity and cushion for the active SnS2 nanoplatelets during Na-ion insertion and extraction processes.