• 文献标题:   Reduced Graphene Oxide-Coated Separator to Activate Dead Potassium for Efficient Potassium Batteries
  • 文献类型:   Article
  • 作  者:   SI LP, WANG JY, XU XJ
  • 作者关键词:   separator, reduced graphene oxide, potassium metal batterie, dead k
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/ma15165505
  • 出版年:   2022

▎ 摘  要

Potassium (K) metal batteries (KMBs) have the advantages of relatively low electric potential (-2.93 V), high specific capacity (687 mAh g(-1)), and low cost, which are highly appealing to manufacturers of portable electric products and vehicles. However, the large amounts of "dead K" caused by K dendrite growth and volumetric expansion can cause severe K metal anode deactivation. Here, a thin layer of conductive reduced graphene oxide (rGO) was coated on a GF separator (rGO@GF) to activate the generated dead K. Compared with the batteries adopting an original separator, those adopting a modified separator have significantly improved specific capacity and cycling stability. The life of full-cell of KMBs combining an rGO@GF separator with synthesized K0.51V2O5 is expected to exceed 400 cycles, with an initial capacity of 92 mAh g(-1) at 0.5 A g(-1) and an attenuation rate per cycle as low as 0.03%. Our work demonstrates that a composite separator of high conductivity is beneficial for high performance KMBs.