• 文献标题:   Influence of graphene reinforcement in conductive polymer: Synthesis and characterization
  • 文献类型:   Review
  • 作  者:   DHAKAL DR, LAMICHHANE P, MISHRA K, NELSON TL, VAIDYANATHAN RK
  • 作者关键词:   conductive polymer, dma, glass transition temperature, graphene, tga
  • 出版物名称:   POLYMERS FOR ADVANCED TECHNOLOGIES
  • ISSN:   1042-7147 EI 1099-1581
  • 通讯作者地址:   Oklahoma State Univ
  • 被引频次:   2
  • DOI:   10.1002/pat.4650
  • 出版年:   2019

▎ 摘  要

Lightweight conductive polymers are considered for lightning strike mitigation in composites by synthesizing intrinsically conductive polymers (ICPs) and by the inclusion of conductive fillers in insulating matrices. Conductive films based on polyaniline (PANI) and graphene have been developed to improve through-thickness conductivity of polymer composites. The result shows that the conductivity of PANI enhanced by blending polyvinylpyrrolidone (PVP) and PANI in 3:1 ratio. Conductive composite thin films are prepared by dispersing graphene in PANI. The conductivity of composite films was found to increase by 40x at 20 wt% of graphene inclusion compared with PVP and PANI blend. Fourier-transform-infrared (FTIR) spectra confirmed in situ polymerization of the polymer blend. The inclusion of graphene also exhibits an increase in Tg by 21 degrees C. Graphene additions also showed an increase in thermal stability by approximately 148 degrees C in the composite films. The mechanical result obtained from DMA shows that inclusion of graphene increases the tensile strength by 48% at 20 wt% of graphene reinforcement. A thin, highly conductive surface that is compatible with a composite resin system can enhance the surface conductivity of composites, improving its lightning strike mitigation capabilities.