• 文献标题:   Highly Conductive Nitrogen-Doped Graphene Grown on Glass toward Electrochromic Applications
  • 文献类型:   Article
  • 作  者:   CUI LZ, CHEN XD, LIU BZ, CHEN K, CHEN ZL, QI Y, XIE HH, ZHOU F, RUMMELI MH, ZHANG YF, LIU ZF
  • 作者关键词:   chemical vapor deposition, nitrogendoped graphene, direct growth, graphene glas, electrochromic window
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Peking Univ
  • 被引频次:   8
  • DOI:   10.1021/acsami.8b11579
  • 出版年:   2018

▎ 摘  要

The direct synthesis of low sheet resistance graphene on glass can promote the applications of such intriguing hybrid materials in transparent electronics and energy-related fields. Chemical doping is efficient for tailoring the carrier concentration and the electronic properties of graphene that previously derived from metal substrates. Herein, we report the direct synthesis of S in. uniform nitrogen-doped (N-doped) graphene on the quartz glass through a designed low-pressure chemical vapor deposition (LPCVD) route. Ethanol and methylamine were selected respectively as precursor and dopant for acquiring predominantly graphitic-N-doped graphene. We reveal that by a precise control of growth temperature and thus the doping level the sheet resistance of graphene on glass can be as low as one-half that of nondoped graphene, accompanied by relative high crystal quality and transparency. Significantly, we demonstrate that this scalable, 5 in. uniform N-doped graphene glass can serve as excellent electrode materials for fabricating high performance electrochromic smart windows, featured with a much simplified device structure. This work should pave ways for the direct synthesis and application of the new type graphene-based hybrid material.