• 文献标题:   Robust rope supercapacitor constructed by programmed graphene composite fibers with high and stable performance
  • 文献类型:   Article
  • 作  者:   NIE WQ, WENG W, LIU LM, ZHANG S, YANG XD, HU JY, ZHANG Y, LI Q, DING X
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Donghua Univ
  • 被引频次:   5
  • DOI:   10.1016/j.carbon.2019.02.022
  • 出版年:   2019

▎ 摘  要

Scaling up energy with volume is critical for fiber supercapacitors to its practical usage in flexible and wearable electronics, which remains a pressing challenge. Here thick fiber electrodes with hierarchical pores are fabricated by programming hundreds of graphene composite fibers into a rope via scalable twisting and braiding. And a volume-independent energy density is achieved from the fiber to the rope with a tremendous volume surge of 1500 magnifications. Based on this rope, a bulky fiber supercapacitor, labeled as rope supercapacitor, is manufactured with a coaxial format. Moreover, highly integrated tandem rope supercapacitors are facilely assembled by sharing electrodes, which are strong and stable in dynamic usage. Furthermore, an 8-unit rope supercapacitor possesses a record high device energy that is 5 times and 35 times higher than that of the state-of-the-art film and fiber supercapacitors, respectively. The idea here can be extended to other fiber-shaped devices to be scaled up without any performance degrading. (c) 2019 Elsevier Ltd. All rights reserved.