• 文献标题:   Photo-oxidation of Graphene in the Presence of Water
  • 文献类型:   Article
  • 作  者:   MITOMA N, NOUCHI R, TANIGAKI K
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Osaka Prefecture Univ
  • 被引频次:   27
  • DOI:   10.1021/jp305823u
  • 出版年:   2013

▎ 摘  要

Oxygen molecules are found to exhibit non-negligible reactivity with graphene under strong light irradiation in the presence of water. The reaction is triggered by the laser Raman spectroscopy measurement itself, and the D band (ca. 1340 cm(-1)) becomes larger as the laser irradiation is prolonged. The electronic transport properties of the graphene derivative are also investigated and both the electron and hole mobility are found to be reduced. These results are attributed to oxidation of graphene. This primitive modification method can be exploited to manipulate the structural and electronic properties of graphene.