• 文献标题:   Multi-Layer Graphene/SnO2 Nanocomposites as Negative Electrode Materials for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   HOU CC, BRAHMA S, WENG SC, CHANG CC, HUANG JL
  • 作者关键词:   sno2, nanocomposite, lithiumion batterie, multilayer graphene, electrochemical storage
  • 出版物名称:   JOURNAL OF ELECTROCHEMICAL ENERGY CONVERSION STORAGE
  • ISSN:   2381-6872 EI 2381-6910
  • 通讯作者地址:   Natl Cheng Kung Univ
  • 被引频次:   1
  • DOI:   10.1115/1.4045155
  • 出版年:   2020

▎ 摘  要

We report the synthesis of SnO2/multi-layer graphene nanocomposites by an easy low temperature (60 degrees C) electroless plating route. An aqueous suspension containing Sn(BF4)(2) with multi-layer graphene is reacted at 60 degrees C in an acidic environment for 1 h, and Na2S2O4 is used to reduce tin ion from Sn(BF4)(2). After electroless plating, the presence of SnO2 particle (15-35 nm) attached to the multi-layer graphene is confirmed by transmission electron microscopy. Tin oxide (SnO2) can be used to modify multi-layer graphene via electroless plating process decorating with oxygen-containing functional groups. It is found that the electroless plating has enhanced the electrochemical performance of SnO2 and multi-layer graphene that shows reasonably good capacity (similar to 243 mAh g(-1) after 50 charge/discharge cycles) and high Coulombic efficiency (similar to 78%).