• 文献标题:   Nitrogen-doped functional graphene nanocomposites for capacitive deionization of NaCl aqueous solutions
  • 文献类型:   Article
  • 作  者:   WEI YC, HUO YQ, TIAN GY, MENG QH, CAO B
  • 作者关键词:   nitrogen doping, graphene nanocomposite, electrode material, capacitive deionization cdi, electrosorption capacity
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   6
  • DOI:   10.1007/s10008-016-3251-2
  • 出版年:   2016

▎ 摘  要

Nitrogen-doped functional graphene nanocomposites (GO-MRF-x) for electrode materials in a capacitive deionization (CDI) application were conveniently prepared through a sol-gel polycondensation reaction catalyzed by Na2CO3 under ambient pressure drying. The materials showed high surface functionalization (N and O groups) which were confirmed by X-ray photoelectron spectroscopy (XPS). The molar ratio of melamine with resorcinol had a marked effect on the specific surface area and porosity of the nanocomposites. The characterization results showed that with the specific surface area of 387 m(2) g(-1) and N content of 7.26 wt%, laminated GO-MRF-0.8 material exhibited a good performance with high specific capacitance (222 F g(-1)), low charge-transfer resistance (0.10 a"broken vertical bar), and electrosorption capacity (16.72 mg g(-1)). Furthermore, the electrosorption isotherms were studied, and it was found that the ion electrosorption behavior of NaCl on GO-MRF-0 followed multilayer adsorption, whereas GO-MRF-0.8 exhibited a change from monolayer to multilayer.