• 文献标题:   Carbon-coated Si nanoparticles/reduced graphene oxide multilayer anchored to nanostructured current collector as lithium-ion battery anode
  • 文献类型:   Article
  • 作  者:   LIU ZJ, GUO PQ, LIU BL, XIE WH, LIU DQ, HE DY
  • 作者关键词:   lithiumion battery, si nanoparticle, reduced graphene oxide, amorphous carbon
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   24
  • DOI:   10.1016/j.apsusc.2016.11.045
  • 出版年:   2017

▎ 摘  要

Silicon is the most promising anode material for the next-generation lithium-ion batteries (LIBs). However, the large volume change during lithiation/delithiation and low intrinsic conductivity hamper its electrochemical performance. Here we report a well-designed LIB anode in which carbon-coated Si nanoparticles/reduced graphene oxide (Si/rGO) multilayer was anchored to nanostructured current collector with stable mechanical support and rapid electron conduction. Furthermore, we improved the integral stability of the electrode through introducing amorphous carbon. The designed anode exhibits superior cyclability, its specific capacity remains above 800 mAh g(-1) after 350 cycles at a current density of 2.0 A g(-1). The excellent electrochemical performance can be attributed to the fact that the Si/rGO multilayer is reinforced by the nanostructured current collector and the formed amorphous carbon, which can maintain the structural and electrical integrities of the electrode. (C) 2016 Elsevier B.V. All rights reserved.