▎ 摘　　要

A well-designed NiCo2S4-based composite has been fabricated by growing a highly active NiCo2S4 nano-architecture on a three-dimensional graphene foam (3DGF) via a facile solvothermal method and performing a subsequent sulfurization reaction. The obtained NiCo2S4@3DGF composites show unique multilevel network-like structures, in which the 3DGF supports network-like building blocks of interconnected NiCo2S4 nanowalls, which are assembled with extensive interconnected ultrathin mesoporous nanosheets. Benefiting from this rational composition combining NiCo2S4 and 3DGF and the well-designed network-like morphology with a high surface area, the obtained composites exhibit excellent electrochemical activities. When used as a free-standing anode for lithium-ion batteries, the composite exhibits a high reversible capacity of 1295 mA h g(-1), even after 150 cycles (at 500 mA g(-1)) and a remarkable rate capability. When used as a catalyst for the oxygen reduction reaction, the composite also exhibits enhanced catalytic activity (4-electron pathway), excellent tolerance to methanol, and high durability, holding great promise as an efficient non-noble-metal catalyst in practical application. In addition, a probable growth mechanism of the NiCo2S4 nanoarchitecture on the surface of 3DGF has been proposed.