• 文献标题:   A Hybrid Material Combined Copper Oxide with Graphene for an Oxygen Reduction Reaction in an Alkaline Medium
  • 文献类型:   Article
  • 作  者:   YU JM, HUANG TZ, JIANG ZK, SUN M, TANG CC
  • 作者关键词:   copper oxide, graphene, electrocatalyst, oxygen reduction reaction, alkaline medium
  • 出版物名称:   MOLECULES
  • ISSN:   1420-3049
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   4
  • DOI:   10.3390/molecules24030441
  • 出版年:   2019

▎ 摘  要

In this work, an electrode material based on CuO nanoparticles (NPs)/graphene (G) is developed for ORR in alkaline medium. According to the characterization of scanning electron microscope and transmission electron microscope, CuO NPs are uniformly distributed on the wrinkled G sheets. The X-ray diffraction test reveals that the phase of CuO is monoclinic. The CuO/G hybrid electrode exhibits a positive onset potential (0.8 V), high cathodic current density (3.79 x 10(-5) mA/cm(2)) and high electron transfer number (four-electron from O-2 to H2O) for ORR in alkaline media. Compared with commercial Pt/C electrocatalyst, the CuO/G electrode also shows superior fuel durability. The high electrocatalytic activity and durability are attribute to the strong coupling between CuO NPs and G nanosheets.