• 文献标题:   Improved Electrochemical Performance of LiMn2O4/Graphene Composite as Cathode Material for Lithium Ion Battery
  • 文献类型:   Article
  • 作  者:   XU HY, CHENG B, WANG YP, ZHENG L, DUAN XH, WANG LH, YANG J, QIAN YT
  • 作者关键词:   limn2o4/graphene, rate capability, lithium ion batterie, composite material, solgel preparation
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   13
  • DOI:  
  • 出版年:   2012

▎ 摘  要

The electrochemical performance especially rate capability of LiMn2O4 is improved by graphene modified via ultrasonic agitation. The pristine LiMn2O4 and LiMn2O4/graphene composite are characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The obtained LiMn2O4/graphene composite shows reversible capacity of 107 mAh g(-1) at 50 C charge/discharge rate. At 55 degrees C, the capacity at 5 degrees C charge/discharge rate for LiMn2O4/graphene is higher than that of pristine LiMn2O4. The electrochemical impedance spectroscopy (EIS) indicates that the charge transfer resistance for LiMn2O4/graphene composite is reduced compared to LiMn2O4 sample.