• 文献标题:   B4C nanosheets decorated with in situ-derived boron-doped graphene quantum dots for high-efficiency ambient N-2 fixation
  • 文献类型:   Article
  • 作  者:   QIU WB, LUO YX, LIANG RP, QIU JD, XIA XH
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Nanchang Univ
  • 被引频次:   15
  • DOI:   10.1039/c9cc03413g
  • 出版年:   2019

▎ 摘  要

In situ-derived boron-doped graphene quantum dots can significantly improve the activity of boron carbide nanosheets for artificial N-2 fixation and reduction with superior electrocatalytic activity (NH3 yield: 28.6 mu g h(-1) mg(cat.)(-1) at -0.45 V vs. RHE; faradaic efficiency: 16.7%), high electrochemical stability, and high selectivity in 0.1 M HCl under ambient conditions.