• 文献标题:   Selective Production of Benzaldehyde Using Metal-Free Reduced Graphene Oxide/Carbon Nitride Hybrid Photocatalysts
  • 文献类型:   Article
  • 作  者:   LIMA MJ, PASTRANAMARTINEZ LM, SAMPAIO MJ, DRAZIC G, SILVA AMT, FARIA JL, SILVA CG
  • 作者关键词:   benzaldehyde, carbon nitride, photocatalysi, reduced graphene oxide, sustainable chemistry
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Univ Porto
  • 被引频次:   1
  • DOI:   10.1002/slct.201800962
  • 出版年:   2018

▎ 摘  要

Benzyl alcohol was selectively oxidized to benzaldehyde in aqueous solution, at ambient conditions of temperature and pressure, by using a photocatalytic approach, with two types of irradiation sources, namely monochromatic UV-A light (392 nm) and visible light (400-700 nm). Conversion after 4 h of reaction was more efficient under UV than under visible, with selectivity in excess of 80% for both irradiating sources. Composites of graphitic carbon nitride (g-C3N4) containing small amounts of reduced graphene oxide (rGO) (up to 1 wt.%) were used as photocatalysts. The presence of rGO was confirmed by spectroscopic and microscopic analyses. Results show that small amounts of rGO phase can considerably enhance the photocatalytic activity of g-C3N4 based catalysts, the best load being 0.10 wt.%. This improvement is attributed to the critical modification of morphological and electronic properties provided by the presence of rGO.