• 文献标题:   High selectivity and effectiveness for removal of tetracycline and its related drug resistance in food wastewater through schwertmannite/graphene oxide catalyzed photo-Fenton-like oxidation
  • 文献类型:   Article
  • 作  者:   MA SJ, JING JN, LIU PY, LI ZC, JIN W, XIE B, ZHAO YP
  • 作者关键词:   food wastewater, schwertmannite/graphene oxide sch/go, photofentonlike system, tetracycline tc, antibiotic resistance
  • 出版物名称:   JOURNAL OF HAZARDOUS MATERIALS
  • ISSN:   0304-3894 EI 1873-3336
  • 通讯作者地址:   East China Normal Univ
  • 被引频次:   2
  • DOI:   10.1016/j.jhazmat.2020.122437
  • 出版年:   2020

▎ 摘  要

Selectively and effectively for removal of tetracycline (TC) and its related antibiotic resistance gene from food wastewater matrix with high-salt and high COD characteristics is highly desirable. In this work, novel schwertmannite/graphene oxide (SCH/GO) nanocomposites were synthesized through a facile oxidation-co-precipitation method. The SCH/GO nanocomposites were characterized by TEM, XRD, BET, PL, DRS, XPS and FTIR. In the presence of 1 mM H2O2, the SCH/GO catalyzed Fenton-like oxidation can thoroughly degrade TC under visible light irradiation, even under nature sunlight, whose second-order kinetic rate constant was about 15 times higher than that of pure SCH. SCH/GO was capable of highly selectively capturing and effectively degrading TC in the presence of similar concentration of Cl-, NO3-, SO42- and PO43- with that of food wastewater, even at organic matters concentration of 12.5 times than that of TC. At the same time, the removal of total organic carbon (TOC) and chemical oxygen demand (COD) in aforementioned food wastewater in SCH/GO + H2O2 + Vis system reached 27.3 % and 34.5 % after 60 min, respectively. The inhibition zone experiments authenticated that the removal of drug resistance of bacteria by TC degradation intermediates can be achieved very well without producing secondary contamination in this system.