• 文献标题:   Self-Assembly of Bi2Te3-Nanoplate/Graphene-Nanosheet Hybrid by One-Pot Route and Its Improved Li-Storage Properties
  • 文献类型:   Article
  • 作  者:   TU FF, XIE J, CAO GS, ZHAO XB
  • 作者关键词:   bismuth telluride, graphene, liion batterie, sandwich
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   15
  • DOI:   10.3390/ma5071275
  • 出版年:   2012

▎ 摘  要

A sandwich structured Bi2Te3-nanoplates/graphene-nanosheet (Bi2Te3/G) hybrid has been synthesized by a facile in situ solvothermal route and has been investigated as a potential anode material for Li-ion batteries. Bi2Te3 grows during the solvothermal process with the simultaneous reduction of graphite oxide into graphene. The in situ formation process of the hybrid has been investigated by X-ray diffraction and X-ray photoelectron spectra. The Li-storage mechanism and performance of Bi2Te3/G and bare Bi2Te3 have been studied by galvanostatic cycling and cyclic voltammetry. The Bi2Te3/G sandwich exhibits an obviously improved cycling stability compared to bare Bi2Te3. The enhancement in electrochemical performance can be attributed to the combined conducting, confining and dispersing effects of graphene for Bi2Te3 nanoplates and to the self-assembled sandwich structure.