• 文献标题:   Upgrading of aromatic compounds in bio-oil over ultrathin graphene encapsulated Ru nanoparticles
  • 文献类型:   Article
  • 作  者:   SHI JJ, ZHAO MS, WANG YY, FU J, LU XY, HOU ZY
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   18
  • DOI:   10.1039/c6ta01317a
  • 出版年:   2016

▎ 摘  要

Fast pyrolysis of biomass for bio-oil production is a direct route to renewable liquid fuels, but raw bio-oil must be upgraded in order to remove easily polymerized compounds (such as phenols and furfurals). Herein, a synthesis strategy for graphene encapsulated Ru nanoparticles (NPs) on carbon sheets (denoted as Ru@G-CS) and their excellent performance for the upgrading of raw bio-oil were reported. Ru@G-CS composites were prepared via the direct pyrolysis of mixed glucose, melamine and RuCl3 at varied temperatures (500-800 degrees C). Characterization indicated that very fine Ru NPs (2.5 +/- 1.0 nm) that were encapsulated within 1-2 layered N-doped graphene were fabricated on N-doped carbon sheets (CS) in Ru@G-CS-700 (pyrolysis at 700 degrees C). And the Ru@G-CS-700 composite was highly active and stable for hydrogenation of unstable components in bio-oil (31 samples including phenols, furfurals and aromatics) even in aqueous media under mild conditions. Thiswork provides a newprotocol to the utilization of biomass, especially for the upgrading of bio-oil.