• 文献标题:   Effect of processing on the stability and electrical properties of pressureless sintered graphene oxide-alumina composites
  • 文献类型:   Article
  • 作  者:   MANISA VK, PORTER M, WHITING MJ, DOREY RA
  • 作者关键词:   graphene oxide, ceramic composite, electrical resistivity, temperature coefficient of resistivity tcr, thermal lifetime
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.ceramint.2022.02.122 EA APR 2022
  • 出版年:   2022

▎ 摘  要

This paper explores the processing of an alumina matrix composite with a percolating network of graphene oxide (GPO), which exhibits a moderate electric resistivity and a near zero temperature coefficient of resistance. Different formulations of GPO-alumina composites were processed using a water-base blending, and, the pellets were densified by pressureless sintering under Argon flow. Electrical conduction at room temperature was achieved in the 2 wt % GPO-alumina composite sintered at 1400 degrees C, and, the 3 wt % GPO-alumina composites sintered at 1400, 1550 and 1700 degrees C. An investigation of the degradation of electrical conductivity was used to identify potential stable operating regimes in which these materials could be used as heaters. Thermogravimetric analysis using the Ozawa-Flynn-Wall method, was used to determine the kinetic parameters of a 3 wt % GPO composite sintered at 1400 degrees C which, had an activation energy for GPO degradation of 195 +/- 68 kJ/mol and, an estimated thermal lifetime of 8.7 +/- 0.8 years for a conversion of 0.5 wt % (failure criterion) at an application temperature of 340 degrees C.