• 文献标题:   Structural Distortions in Few-Layer Graphene Creases
  • 文献类型:   Article
  • 作  者:   ROBERTSON AW, BACHMATIUK A, WU YMA, SCHAFFEL F, BUCHNER B, RUMMELI MH, WARNER JH
  • 作者关键词:   graphene, chemical vapor deposition, apcvd, tem, hrtem
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Univ Oxford
  • 被引频次:   23
  • DOI:   10.1021/nn203763r
  • 出版年:   2011

▎ 摘  要

Folds and creases are frequently found in graphene grown by chemical vapor deposition (CVD), due to the differing thermal expansion coefficients of graphene from the growth catalyst and the flexibility of the sheet during transfer from the catalyst. The structure of a few-layer graphene (FIG) crease is examined by aberration-corrected high-resolution transmission electron microscopy (AC-HRTEM). A study of 2D fast Fourier transforms (FFTs) taken about the region of the crease allowed for the crystal stacking structure of the system to be elucidated. It was found that strain-induced stacking faults were created in the AB Bernal-stacked FIG bulk around the region proximal to the crease termination; this is of interest as the stacking order of FIG is known to have an effect on its electronic properties and thus should be considered when transferring CVD-grown FLG to alternate substrates for electronic device fabrication. The FFTs, along with analysis of the real space images, were used to determine the configuration of the layers in the crease Itself and were corroborated by multislice atomistic TEM simulations. The termination of the crease part way through the FIG sheet is also examined and is found to show strong out of plane distortions in the area about it.