• 文献标题:   Low mass fraction impregnation with graphene oxide (GO) enhances thermo-physical properties of paraffin for heat storage applications
  • 文献类型:   Article
  • 作  者:   RUFUSS DDW, INIYAN S, SUGANTHI L, DAVIES PA
  • 作者关键词:   phase change material, paraffin, graphene oxide, thermal propertie, stability
  • 出版物名称:   THERMOCHIMICA ACTA
  • ISSN:   0040-6031 EI 1872-762X
  • 通讯作者地址:   Aston Univ
  • 被引频次:   6
  • DOI:   10.1016/j.tca.2017.07.005
  • 出版年:   2017

▎ 摘  要

Whereas previous researchers analyzed the thermal behavior of paraffin waxes impregnated with graphene oxide nanoparticles (P-GONP) at high mass fraction ( > 1%), this paper analyzes behavior and stability at only 0.3% mass fraction. 'GONP was prepared by Hummer's method. The morphology was studied using scanning electron microscope (SEM), transmission electron microscope (TEM), X-Ray diffraction (XRD) and Fourier Transformation-Infrared (FT-1R) Spectrometer and the thermal properties were measured using laser flash analyser (LFA), differential scanning calorimetry (DSC), thermo-gravimetric analysis (TGA) and thermal cycling. LFA showed a 101.2% and 94.5% increase in the thermal conductivity of P-GONP compared to pure paraffin (P) in solid and liquid state respectively. Melting and solidifying temperatures and latent heat were found to be 63.5, 59 degrees C & 102 kJ/kg and 57.5, 56 degrees C & 64.7 kJ/kg for P and P-GONP respectively. Thermal cycling over 4000 cycles showed that P-GONP was 27% more stable than P. The latent heat was 64.7 kJ/kg, a 36.5% deterioration compared to virgin paraffin. Compared against higher mass fraction impregnation, lower mass fraction P-GONP was found to have almost equivalent thermo-physical properties (namely thermal conductivity, melting and solidifying characteristics, thermo-chemical stability and reliability) while providing considerable cost saving.