• 文献标题:   Role of an Aluminum Atom on Graphene for Hydrogen Adsorption
  • 文献类型:   Article
  • 作  者:   FUKUSHIMA A, SAWAIRI A, DOI K, SENAMI M, CHEN L, CHENG HS, TACHIBANA A
  • 作者关键词:   graphene, hydrogen, adsorption, aluminum, rigged qed theory
  • 出版物名称:   JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
  • ISSN:   0031-9015
  • 通讯作者地址:   Kyoto Univ
  • 被引频次:   21
  • DOI:   10.1143/JPSJ.80.074705
  • 出版年:   2011

▎ 摘  要

The effects of an aluminum atom on the hydrogen adsorption onto graphene are investigated. An aluminum atom can be attached on a graphene sheet by a bond with both covalent and ionic properties. Then, the electric charge is transferred from the aluminum atom to the graphene. The activation energy for the hydrogen adsorption is significantly lowered by the addition of the aluminum atom for both atomic and molecular adsorptions. The hydrogen adsorption energy is also lowered significantly by the aluminum atom.