• 文献标题:   Synthesis of graphene-encapsulated mesoporous In2O3 with different particle size for high-performance lithium storage
  • 文献类型:   Article
  • 作  者:   ZHAO L, YUE WB, REN Y
  • 作者关键词:   graphene, mesoporous indium oxide, coreshell structure, lithiumion battery
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Beijing Normal Univ
  • 被引频次:   25
  • DOI:   10.1016/j.electacta.2013.11.004
  • 出版年:   2014

▎ 摘  要

Highly ordered and crystalline mesoporous In2O3 was synthesized using KIT-6 as the template and exhibited better electrochemical performance than its bulk counterpart. Moreover, it is interesting to note that the mesoporous In2O3 with small particle size showed enhanced performance compared to that with large particle size. However, the reversible capacity of mesoporous In2O3 still decreased remarkably, possibly owing to the collapse of mesopores during lithiation and delithiation processes. Therefore, these mesoporous In2O3 particles were further wrapped by graphene nanosheets through a stepwise hetero-coagulation method. The graphene encapsulation may enhance the electrical conductivity of the overall electrode, avoid the aggregation of In2O3 particles and even stabilize the mesostructure of In2O3 during cycles, which is beneficial to improving the electrochemical properties of mesoporous In2O3 particles. (C) 2013 Elsevier Ltd. All rights reserved.