• 文献标题:   Electrosynthesis, physioelectrochemical and theoretical investigation of poly ortho aminophenol/magnetic functional graphene oxide nanocomposites as novel and hybrid electrodes for highly capacitive pseudocapacitors
  • 文献类型:   Article
  • 作  者:   EHSANI A, SHIRI HM, KOWSARI E, SAFARI R, SHAYEH JS, BARBARY M
  • 作者关键词:   poap, nanocomposite, supercapacitor, electrosynthesi, functionalized magnetic graphene oxide
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Univ Qom
  • 被引频次:   26
  • DOI:   10.1016/j.jcis.2016.12.003
  • 出版年:   2017

▎ 摘  要

Magnetic functional graphene oxide (MFGO) has been synthesized in this work using FeCl4- magnetic anion paired with 1 -methyl imidazolium cation. Hybrid poly ortho aminophenol (POAP)/MFGO films have then been prepared via POAP electropolymerization in the presence of MFGO nanosheets, serving as active electrodes for electrochemical supercapacitors. The FeC1(4)(-)functional group in MFGO plays a major part in atomic scale charge/energy transfer and consequently intramolecular electrochemical phenomena in MFGO systems, as shown by the theoretical results. POAP/MFGO composite films have been characterized by surface and electrochemical analyses. The performance of the system has been investigated by various electrochemical methods such as galvanostatic charge discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy. Novel nanocomposite compounds have been developed in this work for electrochemical redox capacitors. The advantages of these compounds include simple synthesis method, high active surface area and stability in aqueous electrolytes. (C) 2016 Elsevier Inc. All rights reserved.