• 文献标题:   Facile preparation of poly (diallyldimethylammonium chloride) modified reduced graphene oxide for sensitive detection of nitrite
  • 文献类型:   Article
  • 作  者:   XU FG, DENG M, LIU Y, LING XC, DENG XY, WANG L
  • 作者关键词:   graphene, nitrite, electrochemical sensor, poly diallyldimethylammonium chloride, nanocomposite
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Jiangxi Normal Univ
  • 被引频次:   34
  • DOI:   10.1016/j.elecom.2014.07.016
  • 出版年:   2014

▎ 摘  要

In this communication, a sensitive electrochemical nitrite sensor was constructed based on poly (diallyldimethylammonium chloride) (PDDA) functionalized reduced graphene oxide (PDDA-rGO). The preparation of PDDA-rGO is quite facile, and the PDDA-rGO exhibits good dispersity and high stability in water, together with good conductivity and positive surface charge. All these factors lead to a greatly enhanced catalysis of PDDA-rGO for the nitrite oxidation compared with that of unmodified rGO or bare glassy carbon electrode. Based on PDDA-rGO, an electrochemical nitrite sensor with low overpotential (0.75 V), wide linear range (0.5 mu M-2 mM), low detection limit (0.2 mu M), good stability and selectivity was fabricated, which exhibited satisfied recovery for detecting nitrite in drinking water. (C) 2014 Elsevier B.V. All rights reserved.