• 文献标题:   Facile synthesis of reduced graphene oxide/MWNTs nanocomposite supercapacitor materials tested as electrophoretically deposited films on glassy carbon electrodes
  • 文献类型:   Article
  • 作  者:   CHARTARRAYAWADEE W, MOULTON SE, TOO CO, KIM BC, YEPURI R, ROMEO T, WALLACE GG
  • 作者关键词:   graphene oxide, reduced graphene oxide, carbon nanotube, electrophoretic deposition epd, nanocomposite
  • 出版物名称:   JOURNAL OF APPLIED ELECTROCHEMISTRY
  • ISSN:   0021-891X EI 1572-8838
  • 通讯作者地址:   Univ Wollongong
  • 被引频次:   13
  • DOI:   10.1007/s10800-013-0575-9
  • 出版年:   2013

▎ 摘  要

This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up to 134.3 F g(-1) recorded. This capacitance value is higher than those observed for LAA-reduced GO (LAA-rGO) (63.5 F g(-1)), electrochemically reduced GO (EC-rGO) (27.6 F g(-1)), or electrochemically reduced GO/MWNTs (EC-rGO/MWNTs) (98.4 F g(-1))-based electrodes.