• 文献标题:   Dual coexisting interconnected graphene nanostructures for high performance supercapacitor applications
  • 文献类型:   Article
  • 作  者:   KIM HK, KAMALI AR, ROH KC, KIM KB, FRAY DJ
  • 作者关键词:  
  • 出版物名称:   ENERGY ENVIRONMENTAL SCIENCE
  • ISSN:   1754-5692 EI 1754-5706
  • 通讯作者地址:   Univ Cambridge
  • 被引频次:   41
  • DOI:   10.1039/c6ee00815a
  • 出版年:   2016

▎ 摘  要

A facile and scalable high-temperature molten salt method was used to synthesize a high-quality hierarchical carbon nanostructure consisting of graphene nanosheets and nanoscrolls with an interconnected network and high electrical conductivity. During the process, the intercalation of lithium and hydrogen from molten LiCl into graphite led to the formation of a coexisting graphene sheetscroll nanostructure. An electrode using the fabricated interconnected carbon nanostructure showed a highly reversible specific capacitance of 213 F g(-1) at 1 A g(-1), excellent capacitance retention (84.5% of the initial specific capacitance (1 A g(-1)) at 50 A g(-1)), and good cyclability (97.9% after 10000 cycles). Such remarkable electrochemical performance is desirable for supercapacitor/ultracapacitor applications.