▎ 摘　　要

Because of serious electromagnetic pollution caused by the widespread use of radio frequency equipment, the study of electromagnetic interference (EMI) shielding materials has been a long-standing topic. Carbon fiber and graphene composites have great potential as EMI shielding materials due to their unique microstructure and electrical conductivity. In this work, a novel kind of core-shell composite is fabricated based on the pore-rich pine needles-derived carbon fibers (coded as PNCFs) core and the graphene shell. The pore-rich PNCFs are created by KOH activation, and the integration between the pore-rich PNCFs and the graphene relies on a plasma-enhanced chemical vapor deposition (PECVD) method. The conductivity of the pore-rich PNCFs@graphene core-shell composite reaches 4.97 S cm(-1), and the composite has an excellent EMI shielding effectiveness (SE > 70 dB over X-band (8.2-12.4 GHz)) and achieves a maximum value of similar to 77 dB at 10.4 GHz, which is higher than many biobased EMI shielding materials in the recent literature. By calculation and comparison, the large absorption loss (accounting for 90.8% of total loss) contributes to reducing secondary radiation, which is quite beneficial for stealth uses. Thus, this work demonstrates a promising design method for the preparation of green high-performance composites for EMI shielding and stealth applications (such as warcrafts, missiles, and stealth wears).