• 文献标题:   Microwave absorption and dielectric behavior of lead sulfide - graphene composite nanostructure embedded polyvinylidinedilfuoride thin films
  • 文献类型:   Article
  • 作  者:   DINAKARAN K, NARAYANASAMY K, THEERTHAGIRI S, PEETHAMBARAM P, KRISHNAN S, ROY D
  • 作者关键词:   polyvinylidenedifluoride, lead sulfide nanoparticle, graphene, hybrid nanostructure, polymer nanocomposite, thermal propertie, dielectric studie, electromagnetic interference shielding studie, microwave absorption
  • 出版物名称:   INTERNATIONAL JOURNAL OF POLYMER ANALYSIS CHARACTERIZATION
  • ISSN:   1023-666X EI 1563-5341
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1080/1023666X.2022.2067958 EA APR 2022
  • 出版年:   2022

▎ 摘  要

A lightweight and flexible microwave absorbing composite of polyvinyledine difluoride (PVDF) was fabricated by loading PbS nanocubes embedded Graphene hybrid nanostructures into the PVDF matrix. The PbS embedded graphene nanosheets (PbS/GNs) are synthesized by hydrothermal technique. The PXRD pattern of the PbS, GNS and PbS/GNS suggested face-centered cubic structured PbS loaded GNS nanosheets. FE-SEM images of the graphene-bound lead sulfide octahedral nanocubes are found to have a size of 100 nm and are unvaryingly distributed on the surface of graphene nanosheets. HRTEM image of graphene surface image showing sheet-like structure is embedded with PbS nanocrystals. The PbS/GNs in PVDF matrix were found to exhibit enhanced dielectric constant, reduction in resistivity, and electrical conductivity. The high dielectric constant was exhibited by the 4% GNs dispersed PVDF with a value of 3.7x10(5) and 6% GNs/PbS dispersed PVDF showed 3.5 x10(5) at 1 MHz. The composite PbS/GNs into PVDF exhibit the maximum reflection loss dips in frequency band X for the PbS/Gra/PVDF samples. It is apparent that there are three absorption peaks in the region of 9-12 GHz in which the absorption of -6.9 dB is observed at 10 GHz.