• 文献标题:   Synthesis of V-shaped MnO2 nanostructure and its composites with reduced graphene oxide for supercapacitor application
  • 文献类型:   Article
  • 作  者:   JANGU S, SATPATHY BK, RAJU M, JACOB C, PRADHAN D
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:  
  • 被引频次:   13
  • DOI:   10.1039/d1dt00422k EA APR 2021
  • 出版年:   2021

▎ 摘  要

A unique V-shaped MnO2 nanostructure is synthesized with a weak acid (acetic acid) using the microwave-assisted hydrothermal technique. To improve the performance of MnO2 in supercapacitor applications, its composite was prepared with reduced graphene oxide (rGO), i.e., MnO2/rGO, with different weight ratios of MnO2 and rGO. The specific capacitance values of the as-synthesized V-shaped MnO2 nanostructure and MnO2/rGO nanocomposite were calculated to be 64.75 and 88.95 F g(-1) at a current density of 0.5 A g(-1), respectively, in 1 M Na2SO4 electrolyte. Furthermore, a two-electrode asymmetric supercapacitor device was fabricated using the MnO2/rGO nanocomposite as a positive electrode and activated carbon as a negative electrode. The device has shown energy densities of 25.14 and 17.95 W h kg(-1) at 0.25 and 1 kW kg(-1) power densities, respectively. These values suggest that the MnO2/rGO nanocomposite is a promising material for supercapacitor devices.