• 文献标题:   One-step functionalization of graphene with cyclopentadienyl-capped macromolecules via Diels-Alder "click" chemistry
  • 文献类型:   Article
  • 作  者:   YUAN JC, CHEN GH, WENG WG, XU YZ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428
  • 通讯作者地址:   Huaqiao Univ
  • 被引频次:   36
  • DOI:   10.1039/c2jm16433g
  • 出版年:   2012

▎ 摘  要

Under mild conditions at ambient temperature, as well as at 80 degrees C, graphene chemically converted from graphene oxide was functionalized with cyclopentadienyl (Cp)-capped poly(ethylene glycol) monomethyl ether through a one-step Diels-Alder [4 + 2] (DA) "click" reaction without any catalyst. The resulting material showed improved dispersion properties in various solvents. Spectroscopic tools (Raman, FTIR, XPS, XRD) and nanoscopic scale observations (AFM, SEM, HRTEM) all confirmed the success of the DA reaction. In addition, thermogravimetric analysis (TGA) revealed that the grafting ratios at ambient temperature and at 80 degrees C were 16.7% and 21.8%, respectively.