• 文献标题:   Fabrication of MnO2/graphene oxide composite nanosheets and their application in hydrazine detection
  • 文献类型:   Article
  • 作  者:   LEI JY, LU XF, WANG W, BIAN XJ, XUE YP, WANG C, LI LJ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   60
  • DOI:   10.1039/c2ra01065h
  • 出版年:   2012

▎ 摘  要

MnO2/graphene oxide (GO) composite nanosheets have been successfully fabricated by a simple wet-chemical synthetic route. The composition and structure of the resulting MnO2/GO composites were characterized by transmission electron microscopy (TEM), energy dispersive X-ray diffraction (EDX), Fourier-transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) patterns. The MnO2/GO composite nanosheets exhibited good electrocatalytic behavior in detecting hydrazine at an applied potential of +0.6 V. The sensor showed a good linear dependence on hydrazine concentration in the range of 3 x 10(-6) to 1.12 x 10(-3) with a sensitivity of 1007 mu A mM(-1) cm(-2). The detection limit is 0.16 mu M at the signal-to-noise ratio of 3. Furthermore, the MnO2/GO modified electrode exhibits freedom from interference by other co-existing electroactive species. These results demonstrate that MnO2/GO composites have great potential in the application of hydrazine detection.