• 文献标题:   An alternative synthesis route to graphene oxide: influence of surface chemistry on charge transport in epoxy-based composites
  • 文献类型:   Article
  • 作  者:   VRYONIS O, ANDRITSCH T, VAUGHAN AS, LEWIN PL
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Univ Southampton
  • 被引频次:   5
  • DOI:   10.1007/s10853-019-03477-w
  • 出版年:   2019

▎ 摘  要

A synthetic route for the production of graphene oxide is described, in which the commonly used potassium permanganate (KMnO4) is replaced by chromium trioxide (CrO3) as the oxidizing agent. Raman spectroscopy, thermogravimetric analysis and X-ray photoelectron spectroscopy demonstrate that the product is characterized by a reduced level of oxidation and a reduced defect content, compared to conventional graphene oxide (GO). We therefore term the product moderately oxidized graphene oxide (mGO). In comparison with GO, it is shown that when introduced into an epoxy matrix, mGO offers significant potential benefits. These include: excellent compatibility with the epoxy matrix leading to a low percolation threshold for electrical conductivity (similar to 0.5vol%); an associated increase in electrical conductivity of about eight orders of magnitude; no adverse influence on the epoxy curing reactions; potentially simplified material processing strategies.