• 文献标题:   Electrochemical Determination of Bisphenol A in Saliva by a Novel Three-Dimensional (3D) Printed Gold-Reduced Graphene Oxide (rGO) Composite Paste Electrode
  • 文献类型:   Article
  • 作  者:   GUGOASA LA, STEFANVAN STADEN RI, VAN STADEN JF, COROS M, PRUNEANU S
  • 作者关键词:   bisphenol a bpa, cyclic voltammetry cv, differential pulse voltammetry dpv, reduced graphene oxide rgo, threedimensional 3d printing
  • 出版物名称:   ANALYTICAL LETTERS
  • ISSN:   0003-2719 EI 1532-236X
  • 通讯作者地址:   Natl Inst Res Electrochem Condensed Matter
  • 被引频次:   7
  • DOI:   10.1080/00032719.2019.1620262 EA MAY 2019
  • 出版年:   2019

▎ 摘  要

A novel synthesized gold (Au)-reduced graphene oxide composite (rGO) was used for the fabrication of an electroactive paste inserted in a three-dimensional (3D)-printed platform for the determination of bisphenol A (BPA). The proposed method exhibits good response towards oxidation of BPA in the linear concentration range from 1.00 x 10(-7) mol L-1 to 1.00 x 10(-2) mol L-1. The Au-rGO based 3D-printed platform determined BPA with a detection limit of 3.52 x 10(-9) mol L-1, in comparison with rGO based 3D-printed platform, where the limit of detection was 3.05 x 10(-6) mol L-1. Gold modification of rGO improves the sensitivity and electrochemical behavior of the material for BPA oxidation. The method was validated using five saliva samples collected from children.