• 文献标题:   A new composite based on graphene oxide-poly 3-aminophenol for solid-phase microextraction of four triazole fungicides in water and fruit juices prior to high-performance liquid chromatography analysis
  • 文献类型:   Article
  • 作  者:   KADIVAR M, ALIAKBAR A
  • 作者关键词:   poly aminophenol, triazole fungicide, highperformance liquid chromatography, solidphase microextraction, water fruit juices analysi
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:   Univ Guilan
  • 被引频次:   5
  • DOI:   10.1016/j.foodchem.2019.125127
  • 出版年:   2019

▎ 摘  要

An environmentally friendly method which is based on preparation and use of a new composite consisting of poly 3-aminophenol and graphene oxide for solid-phase microextraction of triazole fungicides from natural water and juices is introduced. The composite was synthesized by in-situ polymerization of 3-aminophenol and graphene oxide in weak alkaline media. By using the obtained results from the characterization, a suitable mechanism for polymerization and a proper structure for the polymer were proposed. Under optimal conditions, there are linear relationships between concentration of triazoles and their HPLC peak areas in the range of 0.5-100 mu g L-1. The recovery percentages, pre-concentration factors and LOQ for all triazoles were 95.2-98.0%, about 200 and 0.2-0.4 mu g L-1, respectively. The offered method was applied for extraction and determination of triazoles from natural water, some juices and it represents a promising alternative method for analysis of triazoles.