• 文献标题:   Exfoliation of Non-Oxidized Graphene Flakes for Scalable Conductive Film
  • 文献类型:   Article
  • 作  者:   PARK KH, KIM BH, SONG SH, KWON J, KONG BS, KANG K, JEON S
  • 作者关键词:   graphene, graphite intercalation compound, conductive thin film, eutectic point, display
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   110
  • DOI:   10.1021/nl3004732
  • 出版年:   2012

▎ 摘  要

The increasing demand for graphene has required a new route for its mass production without causing extreme damages. Here we demonstrate a simple and cost-effective intercalation based exfoliation method for preparing high quality graphene flakes, which form a stable dispersion in organic solvents without any functionalization and surfactant. Successful intercalation of alkali metal between graphite interlayers through liquid-state diffusion from ternary KCl-NaCl-ZnCl2 eutectic system is confirmed by X-ray diffraction and X-ray photoelectric spectroscopy. Chemical composition and morphology analyses prove that the graphene flakes preserve their intrinsic properties without any degradation. The graphene flakes remain dispersed in a mixture of pyridine and salts for more than 6 months. We apply these results to produce transparent conducting (similar to 930 Omega/rectangle at similar to 75% transmission) graphene films using the modified Langmuir-Blodgett method. The overall results suggest that our method can be a scalable (>1 g/batch) and economical route for the synthesis of nonoxidized graphene flakes.