• 文献标题:   Facile Synthesis and Electrochemical Performance of Graphene-Modified Cu2O Nanocomposite for Use in Enzyme-Free Glucose Biosensor
  • 文献类型:   Article
  • 作  者:   FOROUGHI F, RAHSEPAR M, HADIANFARD MJ, KIM H
  • 作者关键词:   electrochemical biosensor, nonenzymatic sensor, graphene, cu2o, glucose.
  • 出版物名称:   IRANIAN JOURNAL OF CHEMISTRY CHEMICAL ENGINEERINGINTERNATIONAL ENGLISH EDITION
  • ISSN:   1021-9986
  • 通讯作者地址:   Shiraz Univ
  • 被引频次:   0
  • DOI:   10.30492/IJCCE.2020.33683
  • 出版年:   2020

▎ 摘  要

Graphene-modified Cu2O nanocomposite was synthesized under facile microwave irradiation of an aqueous solution and has been investigated as an enzyme-free glucose biosensor. Morphology and crystal structure of the graphene-modified Cu2O nanocomposite were investigated by using electron microscopy and X-Ray Diffraction (XRD) analyses. Also, the electrochemical performance of the graphene-modified Cu2O nanocomposite for the measurement of glucose concentration in alkaline media was evaluated by using cyclic voltammetry and chronoamperometric measurements. The electrochemical studies revealed that graphene-modified nanocomposite electrode exhibited a high performance for non-enzymatic oxidation of glucose with a desirable sensitivity. Also, the fabricated graphene-modified biosensor exhibited a wide linear response for glucose detection in the concentrations ranges from 2 mu M to 12 mM and a desirable detection limit of 2 mu M. Also, the graphene-modified Cu2O nanocomposite provided an appropriate selective response for glucose detection in the presence of high concentrations of ascorbic acid and dopamine.