• 文献标题:   Sulfur/nitrogen dual-doped three-dimensional reduced graphene oxide modified with mesoporous TiO2 nanoparticles for promising lithium-ion battery anodes
  • 文献类型:   Article
  • 作  者:   HUO JH, REN YJ, XUE YJ, LIU Y, GUO SW
  • 作者关键词:   threedimensional, reduced graphene oxide, mesoporous tio2, anode, liion batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   12
  • DOI:   10.1016/j.jallcom.2021.159183 EA FEB 2021
  • 出版年:   2021

▎ 摘  要

Three-dimensional graphene is often used as electrode materials due to its excellent electrochemical properties. In this work, sulfur/nitrogen dual-doped reduced graphene oxide (SNG) foam is prepared by a simple sol-gel method with L-cysteine. Furthermore, mesoporous dioxide-titanium (TiO2) nanoparticles are deposited on the surface of SNG at 60 degrees C to improve the Li+ ions diffusion kinetics. As an anode material for lithium ion batteries, the SNG/TiO2 has an excellent reversible discharging capacity (444 mAh g(-1), 0.1 A g(-1)) and good rate capability (217 mAh g(-1), 2.0 A g(-1)). In addition, the SNG/TiO2 electrode delivers a specific capacity as high as 148.8 mAh g(-1) at a current density of 1.0 A g(-1) after 1000 cycles, and even at a high current density of 5.0 A g(-1), a reversible capacity of 99 mAh g(-1) can also be achieved. Hence, the SNG/TiO2 composite synthesized by a simple template-free method at a low-temperature is a promising anode material for lithium ion batteries. (C) 2021 Elsevier B.V. All rights reserved.