• 文献标题:   Effects of a graphene nanosheet conductive additive on the high-capacity lithium-excess manganese-nickel oxide cathodes of lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN WC, HSIEH CY, WENG YT, LI FS, WU HC, WU NL
  • 作者关键词:   graphene, lithiumexcess layered oxide, cathode, conductive additive
  • 出版物名称:   JOURNAL OF APPLIED ELECTROCHEMISTRY
  • ISSN:   0021-891X EI 1572-8838
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   8
  • DOI:   10.1007/s10800-014-0735-6
  • 出版年:   2014

▎ 摘  要

This study examines the effects of a graphene nanosheet (GNS) conductive additive on the performance of a highly packed (2.5 g cm(-3)) lithium-ion battery cathode containing 92 wt% Li-1.1(Mn0.6Ni0.4)(0.9)O-2 microspheres (approximately 6 mu m in diameter). GNSs, approximately 2.0 nm thick and 0.5-1.0 mu m in width, are introduced into an electrode slurry in the form of a dispersion in N-Methyl-2-pyrrolidone. They are substantially smaller than the oxide particles; therefore, their presence exerts no adverse influence on the packing density of the electrode. A small quantity of the GNS additive (