• 文献标题:   A disposable electrochemical sensor for the determination of indole-3-acetic acid based on poly(safranine T)-reduced graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   GAN T, HU CG, CHEN ZL, HU SS
  • 作者关键词:   indole3acetic acid, reduced graphene oxide, poly safranine t, electropolymerization, electrochemical sensor
  • 出版物名称:   TALANTA
  • ISSN:   0039-9140
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   40
  • DOI:   10.1016/j.talanta.2011.03.070
  • 出版年:   2011

▎ 摘  要

A disposable electrochemical sensor for the determination of indole-3-acetic acid (IAA) based on nanocomposites of reduced graphene oxide (rGO) and poly(safranine T) (PST) was reported. The sensor was prepared by coating a rGO film on a pre-anodized graphite electrode (AGE) through dipping-drying and electrodepositing a uniform PST layer on the rGO film. Scanning electron microscopic (SEM) and infrared spectroscopic (IR) characterizations indicated that PST-rGO formed a rough and crumpled composite film on AGE, which exhibited high sensitive response for the oxidation of IAA with 147-fold enhancement of the current signal compared with bare AGE. The voltammetric current has a good linear relationship with IAA concentration in the range 1.0 x 10(-7)-7.0 x 10(-6) M, with a low detection limit of 5.0 x 10(-8) M. This sensor has been applied to the determination of IAA in the extract samples of several plant leaves and the recoveries varied in the range of 97.71-103.43%. (C) 2011 Elsevier B.V. All rights reserved.