• 文献标题:   Durability investigation of graphene-supported Pt nanocatalysts for PEM fuel cells
  • 文献类型:   Article
  • 作  者:   WU HM, WEXLER D, LIU HK
  • 作者关键词:   oxygen reduction, durability, graphene, pem fuel cell, carbon black
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Hubei Univ
  • 被引频次:   39
  • DOI:   10.1007/s10008-011-1317-8
  • 出版年:   2011

▎ 摘  要

We report graphene nanosheets as a durable alternative support material for Pt nanoparticle catalysts for oxygen reduction in proton exchange membrane (PEM) fuel cells and compared them to XC-72. The materials were characterized by X-ray diffraction and transmission electron microscopy. Electrochemical surface oxidation of XC-72 and graphene, and of Pt/XC-72 and Pt/graphene has been compared following treatments for up to 120 h. The electrochemical performance of the specimens was evaluated by cyclic voltammetry and linear sweep voltammetry at different surface oxidation time intervals. Electrochemical measurements indicate that the graphene exihibits greatly enhanced electrochemical durability. It is suggested that graphene nanosheet is a promising, low-cost, and durable electrocatalyst support for oxygen reduction in the PEM fuel cell.