• 文献标题:   Preparation of Ferrocene Functionalized Graphene Modified Electrode and Its Application in Detection of Dopamine
  • 文献类型:   Article
  • 作  者:   LIU C, HE JX, GU NY, JIANXIN C, WANG XL, YANG ZY
  • 作者关键词:   ferrocene, electrochemically reduced graphene oxide, dopamine, electrochemical determination
  • 出版物名称:   CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
  • ISSN:   0253-3820 EI 1872-2040
  • 通讯作者地址:   Sch Resources Environm Chem Engn
  • 被引频次:   1
  • DOI:  
  • 出版年:   2015

▎ 摘  要

A complex of ferrocene functionalized graphene oxide (Fc/GO) was prepared through Friedel. Crafts acylation method and characterized by tunable electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The Fc/GO complex was immobilized on glassy carbon electrode (GCE) with Nafion, and electrochemically reduced by potentiostatic reduction method to get Fc/ ERGO/GCE. The results showed that the obtained Fc/ERGO/GCE had good catalytic performance for the oxidation. reduction of dopamine (DA). A pair of peaks near 0. 2 V in the cyclic voltammogram attributed to DA was observed. The differential pulse voltammetric (DPV) peak current was proportional to the concentration of DA in the range from 0. 4 mu mol/L to 300 mu mol/L (R-2 = 0. 9998), with a limit of detection of 0.08 mu mol/L. The recoveries of DA in the spiked human urine samples were 92. 5% -105. 0% with relative standard derivations (RSDs) of less than 5% (n = 5), which indicated that the fabricated Fc/ERGO/GCE was suitable for the determination of dopamine in real samples.