• 文献标题:   Facile Synthesis of Reduced Graphene Oxide In-situ Wrapped MnTiO3 Nanoparticles for Excellent Lithium Storage
  • 文献类型:   Article
  • 作  者:   LIU HL, ZHAO W, LI RZ, HUANG XY, TANG YF, LI DM, HUANG FQ
  • 作者关键词:   insitu wrapped, reduced oxide graphene, mntio3 nanoparticle, lithiumion batteries anode
  • 出版物名称:   JOURNAL OF INORGANIC MATERIALS
  • ISSN:   1000-324X
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   1
  • DOI:   10.15541/jim20180143
  • 出版年:   2018

▎ 摘  要

The stable high-capacity anode has been an urgent demand for high energy density lithium-ion batteries (LIBs). Herein, a simple and effective strategy to synthesize high-performance reduced graphene oxide (rGO) in-situ wrapped MnTiO3 nanoparticles (MnTiO3@rGO) by Sol-Gel method is designed. The MnTiO3 nanoparticles are uniformly dispersed and wrapped by few-layer graphene. Due to high conductivity of rGO, MnTiO3@rGO nanoparticles show excellent rate performance, with a specific capacity of 286 mAh.g(-1) being displayed at the higher rate of 5.0A.g(-1). Moreover, benefited from porous structure and flexible rGO shell, the MnTiO3@rGO anode delivers a remarkable long-term cycling stability. The specific capacity maintains 441 mAh.g(-1) after 500 cycles at 0.5 A.g(-1), only losing 8.4%. Therefore, the results demonstrate that the facile synthetic strategy is highly desirable for improving the conductivity and stability of metal oxide anodes.