• 文献标题:   Vertically aligned architecture in the dense and thick TiO2-graphene nanosheet electrode towards high volumetric and areal capacities
  • 文献类型:   Article
  • 作  者:   XU CY, KOU XD, LIU DD, FANG HT
  • 作者关键词:   vertically aligned architecture, dense thick electrode, 2d nanomaterial, lithiumion batterie, high volumetric areal capacitie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.electacta.2021.137770 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

2D nanomaterials have attracted intensive attention in the area of compact energy storage owing to their large packing densities. However, the highly tortuous and lengthy channels in conventional 2D nanomaterial electrodes cause sluggish ion diffusion kinetics and seriously reduce the capacity. Herein, we report a simple method adopting diamond wire saw cutting technology to construct a compact vertically aligned TiO2-graphene nanosheet electrode (VATiO(2)-G) with a large thickness of 130 mu m. The vertical alignment not only provides short and less tortuous ion transport pathways to facilitate ion diffusion kinetics, but also improves the electronic conductivity to promote electron transport across the electrode. Accordingly, the VATiO(2)-G anode for lithium-ion batteries simultaneously exhibits high volumetric and areal capacities of 243 mA h cm(-3) and 3.16 mA h cm(-2) at 2.8 mA cm(-2), respectively. This work exploits a general method to attain vertically aligned architecture in dense and thick 2D nanomaterial electrodes. (C) 2021 Elsevier Ltd. All rights reserved.