▎ 摘 要
The chemical vapor deposition of carbon onto a commercial alpha-Al2O3 powder bed produces a pristine film of fewlayered-graphene (FLG) uniformly covering the alpha-Al2O3 grains. This obviates both the manipulation of nano carbons, lengthy mixing steps and the risk of damaging any pre-existing graphene platelets. The powders are consolidated to 99 % by SPS, producing samples where a FLG film is located along the grain boundaries of the submicron alpha-Al2O3. Compared to the pure alpha-Al2O3, the composites are moderately stronger and similarly tough and hard due to crack-deflection and crack-bridging and they are electrically conducting with a percolation threshold below 0.74 vol.% of carbon. The high conductivity values reflect the high quality of the thin FLG film and its continuous nature over very long distances. The samples are characterized by Raman spectroscopy, X-ray photoelectron spectroscopy, scanning and transmission electron microscopy.