• 文献标题:   One-step synthesis of few-layered-graphene/alumina powders for strong and tough composites with high electrical conductivity
  • 文献类型:   Article
  • 作  者:   WEIBEL A, FLAUREAU A, PHAM A, CHEVALLIER G, ESVAN J, ESTOURNES C, LAURENT C
  • 作者关键词:   fewlayeredgraphene, alumina, cvd, nanocomposite, mechanical electrical propertie
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   Univ Toulouse 3 Paul Sabatier
  • 被引频次:   0
  • DOI:   10.1016/j.jeurceramsoc.2020.06.029
  • 出版年:   2020

▎ 摘  要

The chemical vapor deposition of carbon onto a commercial alpha-Al2O3 powder bed produces a pristine film of fewlayered-graphene (FLG) uniformly covering the alpha-Al2O3 grains. This obviates both the manipulation of nano carbons, lengthy mixing steps and the risk of damaging any pre-existing graphene platelets. The powders are consolidated to 99 % by SPS, producing samples where a FLG film is located along the grain boundaries of the submicron alpha-Al2O3. Compared to the pure alpha-Al2O3, the composites are moderately stronger and similarly tough and hard due to crack-deflection and crack-bridging and they are electrically conducting with a percolation threshold below 0.74 vol.% of carbon. The high conductivity values reflect the high quality of the thin FLG film and its continuous nature over very long distances. The samples are characterized by Raman spectroscopy, X-ray photoelectron spectroscopy, scanning and transmission electron microscopy.