• 文献标题:   Nitrogen-Doped Graphene-Activated Iron-Oxide-Based Nanocatalysts for Selective Transfer Hydrogenation of Nitroarenes
  • 文献类型:   Article
  • 作  者:   JAGADEESH RV, NATTE K, JUNGE H, BELLER M
  • 作者关键词:   iron nanocatalysi, transfer hydrogenation, nitroarene, aniline, formic acid
  • 出版物名称:   ACS CATALYSIS
  • ISSN:   2155-5435
  • 通讯作者地址:   Univ Rostock
  • 被引频次:   65
  • DOI:   10.1021/cs501916p
  • 出版年:   2015

▎ 摘  要

Nanoscaled iron oxides on carbon were modified with nitrogen-doped graphene (NGr) and found to be excellent catalysts for the chemoselective transfer hydrogenation of nitroarenes to anilines. Under standard reaction conditions, a variety of functionalized and structurally diverse anilines, which serve as key building blocks and central intermediates for fine and bulk chemicals, were synthesized in good to excellent yields.