▎ 摘　　要

It is of great practical significance to acquire pyrene-capped polymer, which has proven an excellent dispersant of nanocarbons, in an accessible way. Taking synthesis of pyrene-capped polystyrene (PyPS) as the example, free radical polymerization was demonstrated to be an attractive option to satisfactorily fulfill such mission. For this, a new azo-based pyrenyl compound was designed, synthesized, and used as initiator. The molecular structure of PyPS was studied as a function of polymerization temperature and content of chain transfer agent of 1-dodecanethiol. Following the successful synthesis, a PyPS polymer structured as 1.04 pyrene groups per chain was chosen as dispersant for preparation of graphene. The results showed that 0.2 mg/mL of PyPS in chloroform permits 67.4 g/mL of graphene nanosheets to be prepared by liquid-phase exfoliation of graphite. In contrast, only 8.5 g/mL of graphene nanosheets could be obtained in pure chloroform. (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2175-2185